Resistive Random Access Memory (ReRAM), which is based on oxide materials, is gaining attention as a next-generation memory and neuromorphic computing device. Its fast speeds, data retention ability, and simple structure make it a promising candidate to replace existing memory technologies. KAIST researchers have now clarified the operating principle of this memory, which is expected to provide a key clue for the development of high-performance, high-reliability next-generation memory.
KAIST (President Kwang Hyung Lee) announced on the 2nd of September that a research team led by Professor Seungbum Hong from the Department of Materials Science and Engineering, in collaboration with a research team led by Professor Sang-Hee Ko Park from the same department, has for the first time in the world precisely clarified the operating principle of an oxide-based memory device, which is drawing attention as a core technology for next-generation semiconductors.
Using a 'Multi-modal Scanning Probe Microscope (Multi-modal SPM)' that combines several types of microscopes*, the research team succeeded in simultaneously observing the electron flow channels inside the oxide thin film, the movement of oxygen ions, and changes in surface potential (the distribution of charge on the material's surface). Through this, they clarified the correlation between how current changes and how oxygen defects change during the process of writing and erasing information in the memory.
*Several types of microscopes: Conductive atomic force microscopy (C-AFM) for observing current flow, electrochemical strain microscopy (ESM) for observing oxygen ion movement, and Kelvin probe force microscopy (KPFM) for observing potential changes.
With this special equipment, the research team directly implemented the process of writing and erasing information in the memory by applying an electrical signal to a titanium dioxide (TiO2) thin film, confirming at the nano-level that the reason for the current changes was the variation in the distribution of oxygen defects.
In this process, they confirmed that the current flow changes depending on the amount and location of oxygen defects. For example, when there are more oxygen defects, the electron pathway widens, and the current flows well, but conversely, when they scatter, the current is blocked. Through this, they succeeded in precisely visualizing that the distribution of oxygen defects within the oxide determines the on/off state of the memory.
This research was not limited to the distribution at a single point but comprehensively analyzed the changes in current flow, the movement of oxygen ions, and the surface potential distribution after applying an electrical signal over a wide area of several square micrometers (µm2). As a result, they clarified that the process of the memory's resistance changing is not solely due to oxygen defects but is also closely intertwined with the movement of electrons (electronic behavior).
In particular, the research team confirmed that when oxygen ions are injected during the 'erasing process (reset process)', the memory can stably maintain its off state (high resistance state) for a long time. This is a core principle for increasing the reliability of memory devices and is expected to provide an important clue for the future development of stable, next-generation non-volatile memory.
Professor Seungbum Hong of KAIST, who led the research, said, "This is an example that proves we can directly observe the spatial correlation of oxygen defects, ions, and electrons through a multi-modal microscope." He added, "It is expected that this analysis technique will open a new chapter in the research and development of various metal oxide-based next-generation semiconductor devices in the future."
This research, in which Ph.D. candidate Chaewon Gong from the KAIST Department of Materials Science and Engineering participated as the first author, was published on July 20 in 'ACS Applied Materials and Interfaces', a prestigious academic journal in the field of new materials and chemical engineering published by the American Chemical Society (ACS).
※ Paper Title: Spatially Correlated Oxygen Vacancies, Electrons and Conducting Paths in TiO2 Thin Films
This research was carried out with the support of the Ministry of Science and ICT and the National Research Foundation of Korea.